Determination of partial immersion enthalpy in the interaction of water and activated carbon |
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Authors: | Y S Murillo L Giraldo J C Moreno-Piraján |
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Institution: | 1.Departamento de Química, Facultad de Ciencias,Universidad Nacional de Colombia,Bogotá,Colombia;2.Departamento de Química, Facultad de Ciencias,Universidad de los Andes, Grupo de Investigación en Sólidos Porosos y Calorimetría,Bogotá,Colombia |
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Abstract: | A way to calculate the enthalpic contributions of each component of the mixture of activated carbon and water to the immersion
enthalpy using the concepts of the solution enthalpies is presented. By determining the immersion enthalpies of a microporous
activated carbon in water, with values that are between –18.97 and −27.21 Jg−1, from these and the mass ratio of activated carbon and water, differential enthalpies for the activated carbon,
ΔHDIFacH_{{\rm DIF}_{\rm ac}} and water, ΔHDIFwH_{{\rm DIF}_{\rm w}} are calculated, and values between –15.95 and –26.81 Jg−1 and between –19.14 and –42.45 Jg−1, respectively are obtained. For low ratios of the mixture, the components’ contributions to the immersion enthalpy of activated
carbon and water differ by 3.20 Jg−1. |
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Keywords: | |
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