Influence of the conformation of methoxy-(2-naphthyl)acetates (2NMA esters) on their chemical reactions |
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Authors: | Fukuyoshi S Ooi T Kusumi T |
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Affiliation: | Faculty of Pharmaceutical Sciences, Tokushima University, Japan. |
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Abstract: | An SN2 reaction (NaI) of 1,7-di(methanesulfoxyl)heptadien-4-yl methoxy-(2-naphthyl)acetate and a tributyltin hydride reduction of 1,7-diiodo-4-yl methoxy-(2-naphthyl)acetate (2NMA) is crucial for determination of the absolute configuration of secondary alcohols. |
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