Cyclophanes as hosts for aromatic and aliphatic guests |
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| Authors: | Kenji Koga Kazunori Odashima |
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| Affiliation: | (1) Faculty of Pharmaceutical Sciences, University of Tokyo, 113 Hongo, Bunkyo-ku, Tokyo, Japan;(2) Present address: Department of Chemistry, Faculty of Science, Hokkaido University, 060 Sapporo, Japan |
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| Abstract: | A series of water-soluble cyclophanes, made by connecting two diarylmethane units and two bridging chains via four nitrogens, were found to provide hydrophobic cavities of definite shape and size for forming inclusion complexes with various organic compounds in aqueous solution. Some chemical modifications of these cyclophanes are described.This paper is dedicated to Professor D. J. Cram to celebrate his honor in receiving the 1987 Nobel Prize in Chemistry. |
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| Keywords: | Cyclophane aromatic guest aliphatic guest aqueous solution |
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