The influence of correlation of molecular orientations and of molecular flexibility on excess volumes of mixtures of branched and linear alkanes |
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| Authors: | H. Klunder C. L. de Ligny |
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| Affiliation: | (1) Laboratory for Analytical Chemistry, University of Utrecht, Croesestraat 77a, 3522 AD Utrecht, The Netherlands |
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| Abstract: | It is shown that the excess volumes of mixtures of alkanes are not only influenced by equation-of-state effects, but also by differences in orientational order and, probably, in flexibility of the component molecules. |
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| Keywords: | Excess volumes orientational order flexibility torsional oscillations alkanes |
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