A clean, palladium-catalyzed oxidative esterification of aldehydes using benzyl chloride |
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| Authors: | Georgios A HeropoulosCarolina Villalonga-Barber |
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| Institution: | Institute of Organic and Pharmaceutical Chemistry, National Hellenic Research Foundation, Vas. Constantinou Avenue 48, 11635 Athens, Greece |
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| Abstract: | A highly efficient, mild, simple and clean procedure is presented for the one-pot oxidation of aromatic and aliphatic aldehydes to their corresponding ethyl esters using benzyl chloride as the oxidant under palladium-catalyzed conditions. The reaction is complete in just 30 min under microwave irradiation and inert conditions are not required to obtain good to excellent yields (65-93%) of isolated products. |
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| Keywords: | Aldehydes Benzyl chloride Oxidation Esterification Palladium |
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