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Synthesis and characterization of a novel electrical and optical-active triads containing fullerene and perylenebisimide units
Authors:Ning Wang  Yongjun Li  Xiaorong He  Haiyang Gan  Yuliang Li  Changshui Huang  Xinhe Xu  Jinchong Xiao  Shu Wang  Huibiao Liu  Daoben Zhu
Institution:a CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Center for Molecular Sciences, Beijing 100080, People's Republic of China
b Graduate School of Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing 100080, People's Republic of China
Abstract:A new electrical and optical-active triad containing fullerene and perylenebisimide units has been prepared and characterized by UV-vis spectroscopy, fluorescence spectroscopy and voltammetry. For comparison, the triad containing only perylenebisimide units has also been studied. The SEM image indicated that uniform nanofibers of the triad were formed with a diameter of about 50 nm. The thin films of the triad produced steady and prompt photocurrent at irradiation of 20.0 mW cm−2 white light.
Keywords:Fullerene  Electronic properties  Optical properties  Scanning electron microscopy
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