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Covalently linked heterofullerene-porphyrin conjugates; new model systems for long-lived intramolecular charge separation |
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| Authors: | Frank Hauke Dirk M. Guldi Andreas Hirsch |
| Affiliation: | a Institut für Organische Chemie, Henkestrasse 42, D-91054 Erlangen, Germany b Institut für Physikalische Chemie, Egerlandstr 3, D-91058 Erlangen, Germany c Radiation Laboratory, Notre Dame, IN 46556, USA |
| Abstract: | Attaching tetraphenyl porphyrins, with peripheral acetyl or malonate groups, to C59N leads to the first covalently linked heterofullerene-porphyrin conjugates that exhibit long-lived intramolecular charge separation. |
| Keywords: | Fullerenes Porphyrins Fluorescence quenching |
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