| 氨基酸盐酸盐催化二氧化碳与环氧化物的环化反应 |
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| 引用本文： | 江焕峰 袁碧贞 戚朝荣. 氨基酸盐酸盐催化二氧化碳与环氧化物的环化反应[J]. 中国化学, 2008, 26(7): 1305-1308. DOI: 10.1002/cjoc.200890237 |
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| 作者姓名： | 江焕峰 袁碧贞 戚朝荣 |
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| 作者单位： | 广东省广州市华南理工大学化学科学学院绿色化学研究中心 510640 |
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| 摘 要： | 利用氨基酸盐酸盐作为催化剂，二氧化碳可以和环氧化物发生偶联反应，高产率和高选择性地生成环状碳酸酯，详细研究了反应条件如二氧化碳压力，反应温度，时间及催化剂用量对反应的影响。
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| 关 键 词： | 偶联 氨基酸盐酸盐 二氧化碳 环氧化物 环状碳酸酯 |
| 收稿时间： | 2007-10-19 |
| 修稿时间： | 2008-01-08 |
Coupling of Carbon Dioxide with Epoxides Catalyzed by Amino Acid Hydrochloride Salts |
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| Huan‐Feng JIANG,Bi‐Zhen YUAN,Chao‐Rong QI. Coupling of Carbon Dioxide with Epoxides Catalyzed by Amino Acid Hydrochloride Salts[J]. Chinese Journal of Chemistry, 2008, 26(7): 1305-1308. DOI: 10.1002/cjoc.200890237 |
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| Authors: | Huan‐Feng JIANG Bi‐Zhen YUAN Chao‐Rong QI |
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| Affiliation: | 1. Tel.: 0086‐020‐87112906;2. Fax: 0086‐020‐87112906;3. Center of Green Chemistry, College of Chemistry, South China University of Technology, Guangzhou, Guangdong 510640, China |
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| Abstract: | Using amino acid hydrochloride salt as a catalyst, the coupling reaction of CO2 with epoxides could proceed smoothly to give cyclic carbonates in very good yields and high selectivity. The reaction conditions such as the pressure of carbon dioxide, reaction temperature, time and catalyst loading were carefully investigated. |
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| Keywords: | coupling amino acid hydrochloride salt carbon dioxide epoxide cyclic carbonate |
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