Reaction of 1-tert-butyl-3,4-diphenyl-1,2,4-triazol-5-ylidenes with a malonic ester |
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Authors: | Korotkikh Nikolai I Cowley Alan H Moore Jennifer A Glinyanaya Nataliya V Panov Ilia S Rayenko Gennady F Pekhtereva Tatyana M Shvaika Oles P |
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Institution: | The L. M. Litvinenko Institute of Physical Organic and Coal Chemistry, Ukrainian Academy of Sciences, 70 R. Luxemburg, Donetsk 83114, Ukraine. nkorotkikh@ua.fm |
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Abstract: | Four stable carbenes, 1-tert-butyl-3,4-diaryl-1,2,4-triazol-5-ylidenes 1a-d, including new fluorine-containing compounds 1c,d, react with a malonic ester to afford heterocyclic zwitterionic compounds 5a-d. The reactions with more acidic compounds (ethyl acetoacetate, malononitrile and 1,3-dimethylbarbituric acid) proceed with substrate deprotonation to form the respective azolium salts 6a-c. The X-ray crystal structure of 5a was also determined. |
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