Compact simple Lie groups admitting left-invariant Einstein metrics that are not geodesic orbit

In this article, we prove that the compact simple Lie groups $\mathrm{S}\mathrm{U}(n)$ for $n\ge 6$, $\mathrm{S}\mathrm{O}(n)$ for $n\ge 7$, $\mathrm{S}\mathrm{p}(n)$ for $n\ge 3$, ${\mathrm{E}}_6,{\mathrm{E}}_7,{\mathrm{E}}_8$, and ${\mathrm{F}}_4$ admit left-invariant Einstein metrics that are not geodesic orbit. This gives a positive answer to an open problem recently posed by Nikonorov.