| 用~1H-NMR方法研究甲基丙烯酸异冰片酯同N-芳基甲基丙烯酰胺共聚合 |
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| 引用本文： | 丁有骏,齐大荃.用~1H-NMR方法研究甲基丙烯酸异冰片酯同N-芳基甲基丙烯酰胺共聚合[J].北京大学学报(自然科学版),1991(6). |
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| 作者姓名： | 丁有骏 齐大荃 |
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| 作者单位： | 化学系
(丁有骏)，化学系(齐大荃) |
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| 摘 要： | 本文制备的甲基丙烯酸异冰片酯(IBMA)-co-N-芳基甲基丙烯酰胺(N-ArMA)共聚物包括甲基丙烯酸异冰片酯-co-N-对甲苯基甲基丙烯酰胺(IBMA-co-N-p-TMA),甲基丙烯酸异冰片酯-co-N-邻甲苯基甲基丙烯酰胺(IBMA-co-N-o-TMA)和甲基丙烯酸异冰片酯-co-N-对澳苯基甲基丙烯酰胺(IBMA-CO-N-p-BrPhMA)。并用~1H-NMR方法测定了这些共聚物的组成;利用Fineman-Ross方法估算了这些共聚体系中各单体的竞聚率。比较了3种不同酰胺对IBMA的反应活性。
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| 关 键 词： | 甲基丙烯酸异冰片酯 共聚物 N-芳基甲基丙烯酰胺 竞聚率 共聚反应 |
Studied of Copolymerization of Isobornyl-Methacry- late(IBMA) with N-Arylmethacrylamide (N-ArMA) by ~(1)H-NMR Method |
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| DING Youjun,QI Daquan.Studied of Copolymerization of Isobornyl-Methacry- late(IBMA) with N-Arylmethacrylamide (N-ArMA) by ~(1)H-NMR Method[J].Acta Scientiarum Naturalium Universitatis Pekinensis,1991(6). |
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| Authors: | DING Youjun QI Daquan |
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| Abstract: | The IBMA-co-N-ArMA copolymers (include: IBMA-co-N-p-TMA, IBMA-co-N-o-TMA, IBMA-co-N-p-BrPhMA) have been prepared and Their compositions were determined by 1H-NMR spectra.The reactivity ratios were evaluated by means of the Finemen-Ross(F-R)method. |
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| Keywords: | Isobornyl-Methacrylate (IBMA) Copolymer N-Arylmethacrylamide (N-ArMA) Reactivity ratios Copolymerization |
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