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Rhenium sorption by fibrous chitosan-carbon materials
Authors:A. V. Plevaka   I. D. Troshkina   L. A. Zemskova  A. V. Voit
Affiliation:(1) Mendeleev University of Chemical Technology, Miusskaya pl. 9, Moscow, 125190, Russia;(2) Institute of Chemistry, Far-East Division, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022, Russia
Abstract:We studied equilibrium and kinetic characteristics of rhenium sorption by Busofit-based fibrous carbon materials (FCMs) treated electrochemically with recovery potentials varying from −900 to +600 mV from aqueous solutions in the presence of natural biopolymer chitosan. Materials obtained in the anodic potential region and at the open-circuit potential have the best capacity characteristics. The highest rhenium capacity is observed for the material prepared at the recovery potential +600 mV. The relevant sorption isotherm is described by the Langmuir equation with the constant 73.0 ± 8.1 mL/mg; the half-conversion time is 3 min. Original Russian Text ? A.V. Plevaka, I.D. Troshkina, L.A. Zemskova, A.V. Voit, 2009, published in Zhurnal Neorganicheskoi Khimii, 2009, Vol. 54, No. 7, pp. 1229–1232.
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