| Synthesis, Characterization, and Properties of Supported Tungstozincate Bridged by Co(Ⅱ) Complex Fragment |
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| 基金项目： | Supported by the National Natural Science Foundation of China(No.33970842) ; the Analysis and Testing Foundation of Northeast Normal University, China |
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| 摘 要： | CoII(phen)3]2{(ZnW12O40)CoII(phen)2(H2O)}2CoII(trien)2(NaH2O)2]·3H2O was synthesized via hydrothermal technique and characterized with elemental analyses, IR spectroscopy, TGA-DTA, and variable temperature magnetic susceptibility. The compound crystallized in the monoclinic system with the space group P21/n, a=1.8210 nm, b=2.3592 nm, c=2.2932 nm, β=110.31o, V=9.239 nm3, Z=2, R1=0.0827. The compound consists of two coordination cations, three lattice water molecules, and a macroanion {(ZnW12O40)Co(phen)2(...
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| 关 键 词： | 热液合成 有机无机混合物 Keggin结构 钴络合物 |
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