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Diffuse-reflectance Fourier transform-infrared spectroscopic microanalysis of the flavonolignans
Authors:Francisco Martínez  Tomás Adzet  José Iglesias
Institution:(1) Laboratory of Pharmacology and Pharmacognosy, Department of Pharmacology and Chemical Therapeutics, Faculty of Pharmacy, University of Barcelona, Avda. Diagonal s/n, E-08028 Barcelona, Spain;(2) Present address: I. B. ldquoGalileo Galileirdquo, Seminari de Ciències Naturals, C./Molí 57, E-08016 Barcelona, Spain
Abstract:Diffuse-reflectance Fourier transform-infrared spectroscopic (DRIFT) microanalysis (10 mgrg samples) of a selected series of flavonoids was studied, comparing to transmission FT-IR spectroscopic analysis of the same samples at the mg level. DRIFT was shown to be a useful, sample-saving and reliable IR technique for the structural analysis and compound identification of the mainSilybum genus 3-OH-flavonolignans (silybin, isosilybin, silydianin, silychristin and isosilychristin) and the dihydroflavonol taxifolin.
Keywords:diffuse-reflectance infrared spectroscopy  microanalysis  flavonolignans  flavonoids
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