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Ultrasound promoted C-C bond formation: Heck reaction at ambient conditions in room temperature ionic liquids
Authors:Deshmukh R R  Rajagopal R  Srinivasan K V
Affiliation:Organic Chemistry, Technology Division, National Chemical Laboratory, Pune-411 008, India.
Abstract:Heck reaction proceeds at ambient temperature (30 degrees C) with considerably enhanced reaction rate (1.5-3 h) through the formation of Pd-biscarbene complexes and stabilized clusters of zero-valent Pd nanoparticles in ionic liquids under ultrasonic irradiation.
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