Additional of functional vinylzinc reagents to nitrones: synthesis of (E)-N-allylhydroxylamines and their rearrangement into (E)-O-allylhydroxylamines |
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| Authors: | Pandya S U Garçon C Chavant P Y Py S Vallée Y |
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| Affiliation: | LEDSS, UMR 5616, Université J. Fourier, BP53, F-38041 Grenoble, France. |
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| Abstract: | The vinylzinc reagents derived from hydrozirconation of alkynes and transmetallation add readily to nitrones to yield pure (E)-N-allylhydroxylamines; some of these rearrange into O-allylhydroxylamines. |
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