Cerium masquerading as a group 4 element: synthesis,structure and computational characterisation of [CeCl(N(SiMe3)2)3 |
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| Authors: | Eisenstein O Hitchcock P B Hulkes A G Lappert M F Maron L |
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| Institution: | Laboratoire de Structure et de Dynamique des Systèmes Moléculaires et Solides (CNRS UMR 5636), CC 14, Université de Montepellier II, Place Eugène Bataillon, 34095 Montpellier, France. odile.eisenstein@lsd.univ-montp2.fr |
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| Abstract: | Oxidation of the three-coordinate cerium amide Ce(N-(SiMe3)2)3] with TeCl4 in toluene solution yields purple, diamagnetic CeCl(N(SiMe3)2)3], whose structure has been examined by X-ray crystallographic and computational methods. |
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