Ternary cadmium zinc sulphide films with high charge mobilities |
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Affiliation: | 1. Department of Physics, Kwame Nkrumah University of Science and Technology, Kumasi, Ghana;2. Department of Chemistry, Kwame Nkrumah University of Science and Technology, Kumasi, Ghana;3. School of Chemistry, Bangor University, Bangor LL57 2UW, UK;4. School Chemistry and School of Materials, Oxford Road, The University of Manchester, Manchester M139PL, UK;1. Helmholtz-Center Berlin for Materials and Energy (HZB), Hahn-Meitner-Platz 1, 14109 Berlin, Germany;2. BAM Federal Institute for Materials Research and Testing, Richard-Willstaetter-Strasse 11, 12489 Berlin, Germany;3. Department of Chemistry, Humboldt-Universitaet zu Berlin, Brook-Taylor-Strasse 2, 12489 Berlin, Germany;4. CBI Swedish Cement and Concrete Research Institute, Brinellgatan 4, 504 62 Borås, Sweden;1. Thin Film Lab., Faculty of Physics, Semnan University, Semnan, Islamic Republic of Iran;2. Faculty of Physics, Semnan University, Semnan P.O. Box: 35195-363, Islamic Republic of Iran;1. Physics Department, Faculty of Education, Ain Shams University, Cairo, Egypt;2. Physics Department, Faculty of Science, Ain Shams University, Cairo, Egypt;3. Basic Sciences Department, High Institute of Engineering and Techology, El-Arish, North Sinai, Egypt;1. School of Physics and Electronic Electrical Engineering, Huaiyin Normal University, 111 West Chang Jiang Road, Huai''an 223001, China;2. Jiangsu Provincial Key Laboratory of Modern Measurement Technology and Intelligent System, Huai''an 223001, China |
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Abstract: | Cadmium zinc sulphide thin films with high charge mobilities are obtained from acidic chemical baths employing the corresponding metal chlorides, urea and thioacetamide. The films are characterized by powder X-ray diffraction, scanning electron microscopy, energy dispersive X-ray analysis, inductively coupled plasma mass spectrometry, absorption spectroscopy and charge transport measurements. The compositional control afforded by the technique and the resultant changes in the structural, optical and electronic properties of the films are critically examined. We find good correlation between structure and properties at extremes of the composition range. |
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Keywords: | CdZnS Cadmium zinc sulphide Acidic chemical baths Solar cell material Chemical bath deposition |
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