Potentialities of the Voltammetry of 2-Butyne-1,4-diol at Mechanically Renewed Solid Electrodes |
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Authors: | L I Skvortsova T P Aleksandrova V N Kiryushov |
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Institution: | (1) Institute of Solid-State Chemistry and Mechanochemistry, Siberian Division, Russian Academy of Sciences, ul. Kutateladze 18, Novosibirsk, 630128, Russia |
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Abstract: | The electrochemical behavior of 2-butyne-1,4-diol was studied at solid platinum, gold, silver, cobalt, nickel, copper, and graphite electrodes. The working surfaces of the electrodes were renewed by cutting a thin 0.5-µm layer in the test solution immediately before recording every voltammogram. 2-Butyne-1,4-diol was oxidized in alkaline solutions at graphite, nickel, silver, and copper electrodes at positive potentials; the voltammograms obtained at these electrodes were suitable for analytical purposes. The dependence of the anodic current of 2-butyne-1,4-diol on its concentration was linear in the range from 0.03 to 0.3 g/L.__________Translated from Zhurnal Analiticheskoi Khimii, Vol. 60, No. 5, 2005, pp. 499–503.Original Russian Text Copyright © 2005 by Skvortsova, Aleksandrova, Kiryushov. |
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