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Bowl‐like SnO2@Carbon Hollow Particles as an Advanced Anode Material for Lithium‐Ion Batteries
Authors:Jin Liang  Dr Xin‐Yao Yu  Han Zhou  Hao Bin Wu  Prof Shujiang Ding  Xiong Wen Lou
Institution:1. Department of Applied Chemistry, School of Science, MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an 710049 (China);2. School of Chemical and Biomedical Engineering, Nanyang Technological University, 62 Nanyang Drive, Singapore 637459 (Singapore) http://www.ntu.edu.sg/home/xwlou/
Abstract:Despite the great advantages of hollow structures as electrodes for lithium‐ion batteries, one apparent common drawback which is often criticized is their compromised volumetric energy density due to the introduced hollow interior. Here, we design and synthesize bowl‐like SnO2@carbon hollow particles to reduce the excessive hollow interior space while retaining the general advantages of hollow structures. As a result, the tap density can be increased about 30 %. The as‐prepared bowl‐like SnO2@carbon hollow particles with conformal carbon support exhibit excellent lithium storage properties in terms of high capacity, stable cyclability and excellent rate capability.
Keywords:anode materials  hollow nanostructures  lithium‐ion batteries  nanobowls  SnO2
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