Control of Silver(I)–Dialkyl Chalcogenide Coordination by a Synthetic Cavity |
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| Authors: | Dr. Yuh Kohyama Dr. Takashi Murase Prof. Dr. Makoto Fujita |
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| Affiliation: | Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7‐3‐1 Hongo, Bunkyo‐ku, Tokyo 113‐8656 (Japan) |
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| Abstract: | The discrete cavity of a self‐assembled palladium–tris(4‐pyridyl)triazine cage dictates the ratio of metal, ligand, and a non‐coordinative molecule in the formation of silver(I)–dialkyl chalcogenide (Et, nBu; S, Se) complexes and defines their coordination arrangement. |
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| Keywords: | cage compounds chalcogens host– guest systems molecular recognition silver |
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