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A Reliable Aerosol‐Spray‐Assisted Approach to Produce and Optimize Amorphous Metal Oxide Catalysts for Electrochemical Water Splitting
Authors:Long Kuai  Jing Geng  Changyu Chen  Erjie Kan  Yadong Liu  Qing Wang  Prof. Dr. Baoyou Geng
Affiliation:College of Chemistry and Materials Science, The Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecular‐Based Materials, Center for Nano Science and Technology, Anhui Normal University, Wuhu 241000 (P. R. China)
Abstract:
An aerosol‐spray‐assisted approach (ASAA) is proposed and confirmed as a precisely controllable and continuous method to fabricate amorphous mixed metal oxides for electrochemical water splitting. The proportion of metal elements can be accurately controlled to within (5±5) %. The products can be sustainably obtained, which is highly suitable for industrial applications. ASAA was used to show that Fe6Ni10Ox is the best catalyst among the investigated Fe‐Ni‐Ox series with an overpotential of as low as 0.286 V (10 mA cm?2) and a Tafel slope of 48 mV/decade for the electrochemical oxygen evolution reaction. Therefore, this work contributes a versatile, continuous, and reliable way to produce and optimize amorphous metal oxide catalysts.
Keywords:aerosol sprays  heterogeneous catalysis  metal oxides  oxygen evolution reaction  water splitting
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