| Synthesis,Crystal Structure and Characterization of a Cobalt Coordination Polymer： [Co（1,4-ndc）（L） （H2O）]n |
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| 作者姓名： | CHE Guang-Bo ;XU Mao-Liang ;LIU Chun-Bo ;WANG Qing-Wei ;XU Zhan-Lin |
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| 作者单位： | Department of Chemistry Jilin Normal University，Xi'an Modern Chemistry Research Institute，Department of Chemistry Jilin Normal University，Department of Chemistry Jilin Normal University，Department of Chemistry Jilin Normal University，Siping 136000 China Institute of Applied Chemistry Jilin Normal University Siping 136000 China，Xi'an 710065 China，Siping 136000 China Institute of Applied Chemistry Jilin Normal University Siping 136000 China，Siping 136000 China Institute of Applied Chemistry Jilin Normal University Siping 136000 China，Siping 136000 China Institute of Applied Chemistry Jilin Normal University Siping 136000 China |
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| 基金项目： | 吉林省教育厅自然科学基金，吉林师范大学博士基金，Science and Technology Institute Foundation of Siping City，Subject and Base Construction Foundation of Jilin Normal University |
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| 摘 要： | The title coordination polymer, Co（1,4-ndc）（L）（H2O）]n 1 （1,4-H2ndc = 1,4-na- phthalenedicarboxylic acid and L =1-（5-（1H-imidazol- 1-yl）pentyl）- 1H-imidazole） has been hydrothermally synthesized and characterized by IR and single-crystal X-ray diffraction. It crystallizes in monoclinic, space group P21/n with a = 12.4333（12）, b = 13.2963（13）, c = 13.4678（13）A, α =β = 90°, y =107.302（2）°, V= 2125.7（4）A^3, Z = 4, CoC22H22N4O5, Mr = 481.37, De = 1.504 g/cm^3, F（000） = 996, μ（MoKa） = 0.850 mm^-1, R = 0.0472 and wR = 0.0984. Compound 1 exhibits a two-dimensional layer structure. The O-H...O and C-H...O hydrogen bonds stabilize the structure of 1.
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| 关 键 词： | 合成 晶体结构 结构表征 钴配位化合物 配位聚合体 |
Synthesis, Crystal Structure and Characterization of a Cobalt Coordination Polymer: [Co(1,4-ndc)(L) (H2O)]n |
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| CHE Guang-Bo,;XU Mao-Liang,;LIU Chun-Bo,;WANG Qing-Wei,;XU Zhan-Lin.Synthesis, Crystal Structure and Characterization of a Cobalt Coordination Polymer: [Co(1,4-ndc)(L) (H2O)]n[J].Chinese Journal of Structural Chemistry,2008,27(7):773-776. |
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| Authors: | CHE Guang-Bo XU Mao-Liang LIU Chun-Bo WANG Qing-Wei XU Zhan-Lin |
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| Abstract: | The title coordination polymer, Co(l,4-ndc)(L)(H2O)]n1(1,4-H2ndc=1,4-na-phthalenedicarboxylic acid and L = 1-(5-(1H-imidazol-1-yl)pentyl)-1H-imidazole) has been hydrothermally synthesized and characterized by IR and single-crystal X-ray diffraction.It crystallizes in monoclinic, space group P21/n with a = 12.4333(12), b = 13.2963(13), c = 13.4678(13)(A), α =β= 90°,γ=107.302(2)°,V= 2125.7(4)(A)3, Z = 4, CoC22H22N4O5, Mr = 481.37,Dc = 1.504 g/cm3, F(000) = 996,μ(MoKa) = 0.850 mm-1, R = 0.0472 and wR = 0.0984.Compound 1 exhibits a two-dimensional layer structure.The O-H…O and C-H…O hydrogen bonds stabilize the structure of 1. |
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| Keywords: | cobalt complex crystal structure coordination polymer 1 4-naphthalenedicarboxylic acid |
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