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Filling of antibonding orbitals—II Chemical bond properties
Authors:J F A Williams
Institution:

Makerere University College, Kampala, Uganda

Abstract:Antibonding effects, which accompany double-bonding in saturated compounds, account for many chemical bond lengths which are anomalous on the basis of electronegativity. Double-bonding influences the Pauling Electronegativity values of N, O, F, Al and Si and also widens the interbond angles in molecules such as (CH3)3N, (CF3)3N, (CH3)2O and (CF3)2O.
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