Filling of antibonding orbitals—II Chemical bond properties |
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Authors: | J F A Williams |
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Institution: | Makerere University College, Kampala, Uganda |
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Abstract: | Antibonding effects, which accompany double-bonding in saturated compounds, account for many chemical bond lengths which are anomalous on the basis of electronegativity. Double-bonding influences the Pauling Electronegativity values of N, O, F, Al and Si and also widens the interbond angles in molecules such as (CH3)3N, (CF3)3N, (CH3)2O and (CF3)2O. |
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