A mesoporous metal-organic framework constructed from a nanosized C3-symmetric linker and [Cu24(isophthalate)24] cuboctahedra |
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| Authors: | Yan Yong Yang Sihai Blake Alexander J Lewis William Poirier Eric Barnett Sarah A Champness Neil R Schröder Martin |
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| Institution: | School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD, UK. |
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| Abstract: | The mesoporous framework Cu(3)(L)(H(2)O)(3)]·(DMF)(35)·(H(2)O)(35) (NOTT-119) shows on desolvation a BET surface area of 4118(200) m(2) g(-1), a pore volume of 2.35 cm(3) g(-1), a total H(2) uptake of 101 mg g(-1) at 60 bar, 77 K and a total CH(4) uptake of 327 mg g(-1) at 80 bar, 298 K. |
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