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Cross-metathesis reactions of vinyl-chlorins and -porphyrins catalyzed by a "second generation" Grubbs' catalyst
Authors:Liu Xin  Sternberg Ethan  Dolphin David
Affiliation:Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, British Columbia, V6T 1Z1, Canada.
Abstract:The first application of olefin cross-metathesis with vinylchlorins and vinylporphyrins using a "second generation" Grubbs' catalyst is reported. Cross-metathesis products were obtained in good yields with high E-stereoselectivity.
Keywords:
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