A model of reduction mechanism of rhenium in Re/Al2O3 catalysts |
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Authors: | S Engels H Lausch and H -W Meiners |
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Institution: | (1) Sektion Chemie, Technische Hochschule Carl Schorlemmer Leuna-Merseburg, 4200 Merseburg, BRD |
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Abstract: | In Re/Al2O3 there exist a monolayer type of Re and a second one which is inserted in the alumina lattice. The latter is reduced by a two-step mechanism including Re(IV) species.
![Rcy](/content/u194083047p14l41/xxlarge1056.gif) ![iecy](/content/u194083047p14l41/xxlarge1077.gif) ![ncy](/content/u194083047p14l41/xxlarge1085.gif) ![icy](/content/u194083047p14l41/xxlarge1080.gif) Re/Al2O3 ![ncy](/content/u194083047p14l41/xxlarge1085.gif) ![acy](/content/u194083047p14l41/xxlarge1072.gif) ![khcy](/content/u194083047p14l41/xxlarge1093.gif) ![ocy](/content/u194083047p14l41/xxlarge1086.gif) ![dcy](/content/u194083047p14l41/xxlarge1076.gif) ![icy](/content/u194083047p14l41/xxlarge1080.gif) ![tcy](/content/u194083047p14l41/xxlarge1090.gif) ![scy](/content/u194083047p14l41/xxlarge1089.gif) ![vcy](/content/u194083047p14l41/xxlarge1074.gif) ![icy](/content/u194083047p14l41/xxlarge1080.gif) ![dcy](/content/u194083047p14l41/xxlarge1076.gif) ![mcy](/content/u194083047p14l41/xxlarge1084.gif) ![ocy](/content/u194083047p14l41/xxlarge1086.gif) ![ncy](/content/u194083047p14l41/xxlarge1085.gif) ![ocy](/content/u194083047p14l41/xxlarge1086.gif) ![scy](/content/u194083047p14l41/xxlarge1089.gif) ![lcy](/content/u194083047p14l41/xxlarge1083.gif) ![ocy](/content/u194083047p14l41/xxlarge1086.gif) ![vcy](/content/u194083047p14l41/xxlarge1074.gif) ![icy](/content/u194083047p14l41/xxlarge1080.gif) ![dcy](/content/u194083047p14l41/xxlarge1076.gif) ![chcy](/content/u194083047p14l41/xxlarge1095.gif) ![acy](/content/u194083047p14l41/xxlarge1072.gif) ![scy](/content/u194083047p14l41/xxlarge1089.gif) ![tcy](/content/u194083047p14l41/xxlarge1090.gif) ![icy](/content/u194083047p14l41/xxlarge1080.gif) , ![vcy](/content/u194083047p14l41/xxlarge1074.gif) ![scy](/content/u194083047p14l41/xxlarge1089.gif) ![tcy](/content/u194083047p14l41/xxlarge1090.gif) ![rcy](/content/u194083047p14l41/xxlarge1088.gif) ![ocy](/content/u194083047p14l41/xxlarge1086.gif) ![iecy](/content/u194083047p14l41/xxlarge1077.gif) ![ncy](/content/u194083047p14l41/xxlarge1085.gif) ![ncy](/content/u194083047p14l41/xxlarge1085.gif) ![ycy](/content/u194083047p14l41/xxlarge1099.gif) ![rcy](/content/u194083047p14l41/xxlarge1088.gif) ![iecy](/content/u194083047p14l41/xxlarge1077.gif) ![shcy](/content/u194083047p14l41/xxlarge1096.gif) ![iecy](/content/u194083047p14l41/xxlarge1077.gif) ![tcy](/content/u194083047p14l41/xxlarge1090.gif) ![kcy](/content/u194083047p14l41/xxlarge1082.gif) . ![Pcy](/content/u194083047p14l41/xxlarge1055.gif) ![ocy](/content/u194083047p14l41/xxlarge1086.gif) ![scy](/content/u194083047p14l41/xxlarge1089.gif) ![lcy](/content/u194083047p14l41/xxlarge1083.gif) ![iecy](/content/u194083047p14l41/xxlarge1077.gif) ![dcy](/content/u194083047p14l41/xxlarge1076.gif) ![ncy](/content/u194083047p14l41/xxlarge1085.gif) ![icy](/content/u194083047p14l41/xxlarge1080.gif) ![vcy](/content/u194083047p14l41/xxlarge1074.gif) ![ocy](/content/u194083047p14l41/xxlarge1086.gif) ![scy](/content/u194083047p14l41/xxlarge1089.gif) ![scy](/content/u194083047p14l41/xxlarge1089.gif) ![tcy](/content/u194083047p14l41/xxlarge1090.gif) ![acy](/content/u194083047p14l41/xxlarge1072.gif) ![ncy](/content/u194083047p14l41/xxlarge1085.gif) ![acy](/content/u194083047p14l41/xxlarge1072.gif) ![vcy](/content/u194083047p14l41/xxlarge1074.gif) ![lcy](/content/u194083047p14l41/xxlarge1083.gif) ![icy](/content/u194083047p14l41/xxlarge1080.gif) ![vcy](/content/u194083047p14l41/xxlarge1074.gif) ![acy](/content/u194083047p14l41/xxlarge1072.gif) ![iecy](/content/u194083047p14l41/xxlarge1077.gif) ![tcy](/content/u194083047p14l41/xxlarge1090.gif) ![scy](/content/u194083047p14l41/xxlarge1089.gif) ![pcy](/content/u194083047p14l41/xxlarge1087.gif) ![dcy](/content/u194083047p14l41/xxlarge1076.gif) ![vcy](/content/u194083047p14l41/xxlarge1074.gif) ![ucy](/content/u194083047p14l41/xxlarge1091.gif) ![khcy](/content/u194083047p14l41/xxlarge1093.gif) ![scy](/content/u194083047p14l41/xxlarge1089.gif) ![tcy](/content/u194083047p14l41/xxlarge1090.gif) ![ucy](/content/u194083047p14l41/xxlarge1091.gif) ![pcy](/content/u194083047p14l41/xxlarge1087.gif) ![iecy](/content/u194083047p14l41/xxlarge1077.gif) ![ncy](/content/u194083047p14l41/xxlarge1085.gif) ![chcy](/content/u194083047p14l41/xxlarge1095.gif) ![acy](/content/u194083047p14l41/xxlarge1072.gif) ![tcy](/content/u194083047p14l41/xxlarge1090.gif) ![ocy](/content/u194083047p14l41/xxlarge1086.gif) ![mcy](/content/u194083047p14l41/xxlarge1084.gif) ![mcy](/content/u194083047p14l41/xxlarge1084.gif) ![iecy](/content/u194083047p14l41/xxlarge1077.gif) ![khcy](/content/u194083047p14l41/xxlarge1093.gif) ![acy](/content/u194083047p14l41/xxlarge1072.gif) ![ncy](/content/u194083047p14l41/xxlarge1085.gif) ![icy](/content/u194083047p14l41/xxlarge1080.gif) ![zcy](/content/u194083047p14l41/xxlarge1079.gif) ![mcy](/content/u194083047p14l41/xxlarge1084.gif) , ![vcy](/content/u194083047p14l41/xxlarge1074.gif) ![kcy](/content/u194083047p14l41/xxlarge1082.gif) ![lcy](/content/u194083047p14l41/xxlarge1083.gif) ![yucy](/content/u194083047p14l41/xxlarge1102.gif) ![chcy](/content/u194083047p14l41/xxlarge1095.gif) ![acy](/content/u194083047p14l41/xxlarge1072.gif) Re(IV).
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