Catalytic and enantioselective allylic C-H activation with donor-acceptor-substituted carbenoids |
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| Authors: | Davies Huw M L Nikolai Joachim |
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| Affiliation: | Department of Chemistry, University at Buffalo, The State University of New York, Buffalo 14260, USA. hdavies@acsu.buffalo.edu |
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| Abstract: | In this perspective we give an overview of enantioselective C-H activation at allylic sites by means of rhodium(II)-stabilized donor-acceptor-substituted carbenoids. This methodology has been proven to be both an equivalent to established asymmetric reaction sequences and a new synthetic approach with no established counterpart in organic synthesis. |
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