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Vibrational spectroscopic studies on the hofmann-Td-type clathrates: M(NH3)2M′(CN)4·2C6H6 (M=Mn or Cd and M′=Cd or Hg0
Authors:Ergün Kasap  Ziya Kantarci
Institution:(1) Fen Edebiyat Fakültesi, Gazi Üniversitesi, Teknikokullar, 06500 Ankara, Turkey
Abstract:IR spectra of Mn(NH3)2M(CN)4·2C6H6 (M=Cd or Hg), and IR and Raman spectra of Cd(NH3)2M(CN)4·2C6H6 (M=Cd or Hg) are reported. The spectral data suggest that the former two compounds are similar in structure to the latter two Td-type clathrates.
Keywords:Hofmann-Td-type clathrate  inclusion compounds  ammonia  IR spectra  Raman spectra
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