| 光催化氧化丙烯产物的气相色谱分析 |
| |
| 引用本文： | 张纪伟,王晓冬,吕祖芳,金振声.光催化氧化丙烯产物的气相色谱分析[J].化学研究,2009,20(4):69-72. |
| |
| 作者姓名： | 张纪伟 王晓冬 吕祖芳 金振声 |
| |
| 作者单位： | 1. 河南大学,特种功能材料重点实验室,河南,开封,475004
2. 中国科学院,兰州化学物理研究所,甘肃,兰州,730000 |
| |
| 摘 要： | 建立了光催化氧化微量丙烯所产生的CO2和H2O的气相色谱分析检测方法.CO2通过一个装有Ni催化剂的转化炉加氢转化成CH4,H2O通过一个CaC2反应管转化成C2H2,从而可以利用氢火焰离子化检测器（FID）进行微量分析.利用该分析方法能对反应生成的CO2进行定性和定量分析,对反应生成的H2O进行定性分析.实验证明该分析方法的准确度、精密度和灵敏度都能满足实验的要求.有氧气的存在下会出现＂鬼峰＂,文中对这一现象进行了讨论.
|
| 关 键 词： | 光催化氧化 丙烯 气相色谱 二氧化碳 微量分析 鬼峰 |
Analysis of the Photocatalytic Oxidation Products of Propylene by Gas Chromatography |
| |
| ZHANG Ji-wei,WANG Xiao-dong,LV Zu-fang,JIN Zhen-sheng.Analysis of the Photocatalytic Oxidation Products of Propylene by Gas Chromatography[J].Chemical Research,2009,20(4):69-72. |
| |
| Authors: | ZHANG Ji-wei WANG Xiao-dong LV Zu-fang JIN Zhen-sheng |
| |
| Institution: | ZHANG Ji-wei , WANG Xiao-dong, LV Zu-fang, JIN Zhen-sheng ( 1. Laboratory for Special Functional Materials, Henan University, Kaifeng 475004, Henan, China; 2. Lazhon Institute of Chemical Physics, Chirvese Academy of Sciemces, Lanzhou 730000, Gansu, China) |
| |
| Abstract: | A gas chromatography method was established for the product analysis of propylene photocatalytic oxidation.The products CO2 and H2O were converted into CH4 and C2H2respectively and detected using a flame ionization detector(FID).The results show that the method is reliable.The "ghost" peak emerging in the presence of O2 was discussed. |
| |
| Keywords: | photocatalytic oxidation propylene gas chromatography CO2 trace amount analysis ghost peak |
| 本文献已被 维普 万方数据 等数据库收录！ |
|
