| 芳基对硝基苯乙炔基汞的合成 |
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| 引用本文： | 张孝义,吴向东,秦金贵,刘道玉. 芳基对硝基苯乙炔基汞的合成[J]. 高等学校化学学报, 1995, 16(1): 79 |
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| 作者姓名： | 张孝义 吴向东 秦金贵 刘道玉 |
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| 作者单位： | 武汉大学化学系, 武汉 430072 |
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| 基金项目： | 攀登计划资助,国家自然科学基金 |
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| 摘 要： | 采用芳基醋酸汞或芳基氢氧化汞与对硝基苯乙炔在碱性介质中反应,合成了12种新的取代苯基对硝基苯乙炔基汞化合物。紫外可见光诸实验表明此合成反应为可逆反应。通过元素分析及IR、MS、1NMR和UV光谱对化合物结构进行了鉴定。
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| 关 键 词： | 有机汞化合物 合成 鉴定 |
| 收稿时间： | 1994-02-04 |
Synthesis of(4-Nitropphenylacetylenyl)(aryl)mercury |
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| ZHANG Xiao-Yi,WU Xiang-Dong, QIN Jin-Gui, LIU Dao-Yu. Synthesis of(4-Nitropphenylacetylenyl)(aryl)mercury[J]. Chemical Research In Chinese Universities, 1995, 16(1): 79 |
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| Authors: | ZHANG Xiao-Yi WU Xiang-Dong QIN Jin-Gui LIU Dao-Yu |
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| Affiliation: | Department of Chemistry, Wuhan University, Wuhan, 430072 |
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| Abstract: | A series of new(4-nitrophenylacetylenyl)(aryl)mercury compounds were prepared by the reaction of aryl mercury acetate or aryl mercury hydroxide with 4-nitrophenylacetylene under a base condition. The results of ultraviolet absorption spectroscopic study showed that the reaction is reversible.All the compounds were characterized bv means of elementary analysis,IR,1HNMR,electronic and mass spectroscopies. |
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| Keywords: | Organomercuric compound Synthesis Characterization |
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