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Preorganized frustrated Lewis pairs |
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| Authors: | Bertini Federica Lyaskovskyy Volodymyr Timmer Brian J J de Kanter Frans J J Lutz Martin Ehlers Andreas W Slootweg J Chris Lammertsma Koop |
| Institution: | Department of Chemistry and Pharmaceutical Sciences, VU University Amsterdam, De Boelelaan 1083, 1081 HV Amsterdam, The Netherlands. |
| Abstract: | Geminal frustrated Lewis pairs (FLPs) are expected to exhibit increased reactivity when the donor and acceptor sites are perfectly aligned. This is shown for reactions of the nonfluorinated FLP tBu(2)PCH(2)BPh(2) with H(2), CO(2), and isocyanates and supported computationally. |
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