Growth of CdS/ZnS strained layer superlattices on GaAs(0 0 1) by molecular-beam epitaxy with special reference to their structural properties and lattice dynamics
a Institut für Angewandte Physik, Universität Karlsruhe, Kaiserstrasse 12, D-76128 Karlsruhe, Germany
b Physikalisches Institut, Universität Würzburg, Am Hubland, D-97076 Würzburg, Germany
Abstract:
Strained layer CdS/ZnS superlattices have been grown on GaAs(0 0 1) by molecular-beam epitaxy using CdS and ZnS compound sources. The samples were investigated with special reference to their structural properties and lattice dynamics by means of X-ray diffraction and Raman spectroscopy. The results of four superlattices with different period length are discussed in detail. X-ray diffraction profiles show superlattice satellite peaks up to the fourth order indicating a high degree of periodicity. The lateral and in-depth homogeneity of the period length is also confirmed by Raman investigations. Folded longitudinal acoustic phonons in CdS/ZnS superlattices were observed for the first time. The experimental values agree very well with theoretical calculations based on the Rytov model and show the expected dependency on the superlattice period. The behaviour of the optical phonons is mainly determined by strain induced shifts caused by the high lattice mismatch (−7%) for this system. A good agreement between theoretical predictions and detected frequencies is obtained.