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聚多缩乙二醇对苯二酚醚的合成及其色谱性能Ⅰ.
引用本文:束家有,张保华,李彩芹,李彤,李冰.聚多缩乙二醇对苯二酚醚的合成及其色谱性能Ⅰ.[J].应用化学,1991(6).
作者姓名:束家有  张保华  李彩芹  李彤  李冰
作者单位:武汉化工学院化工系,武汉化工学院化工系,武汉化工学院化工系,武汉化工学院化工系,武汉化工学院化工系 武汉 430074,武汉 430074,武汉 430074,武汉 430074,武汉 430074
摘    要:由对苯二酚与二氯甘醇反应合成了一系列聚多缩乙二醇对苯二酚醚,M=2800~4500。这些聚醚是一类高效、广谱性气相色谱固定液,可用于有机混合物的有效分离鉴定。

关 键 词:聚多缩乙二醇对苯二酚醚  合成  气相色谱  固定液

OLIGO(ETHYLENE GLYCOL DI(p-HYDROXYPHENYL)ETHERS)AND THEIR USE AS STATIONARY LIQUIDS FOR GAS CHROMATOGRAPHY
Shu Jiayou,Zhang Baohua,Li Caiqin,Li Tong,Li Bing Wuhan Institute of Chemical Technology,Wuhan.OLIGO(ETHYLENE GLYCOL DI(p-HYDROXYPHENYL)ETHERS)AND THEIR USE AS STATIONARY LIQUIDS FOR GAS CHROMATOGRAPHY[J].Chinese Journal of Applied Chemistry,1991(6).
Authors:Shu Jiayou  Zhang Baohua  Li Caiqin  Li Tong  Li Bing Wuhan Institute of Chemical Technology  Wuhan
Institution:Shu Jiayou,Zhang Baohua,Li Caiqin,Li Tong,Li Bing Wuhan Institute of Chemical Technology,Wuhan 430073
Abstract:The oligomeric ethylene glycol di-p-hydroxyphenyl ethers have been synthesized by Wil-liamson reaction of p-hydroxybenzene with dichloroethane, dichloroethylether, dichlorotrig-lycol dichlorotetraglycol and characterized by IR, UV, ~1H NMR, ~(13)C NMR. The oligomerscan be used as stationary phases in gas chromatography for separation of mixed organiccompounds: alcohols, phenols, amines, esters, and aromatic hydrocarbons.
Keywords:ethylene glycol ether  oligomer  synthesis  gas chromatography  stationary phase
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