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The use of a photoinduced electron-transfer reaction for optical limiting in fullerene-containing solutions
Authors:M V Gryaznova  V V Danilov  A I Khrebtov  T A Shakhverdov
Institution:(1) Research Institute for Laser Physics, Birzhevaya liniya 12, 199034 St. Petersburg, Russia;(2) Vavilov State Optical Institute, All-Russia Research Center, Birzhevaya liniya 12, 199034 St. Petersburg, Russia
Abstract:Optical limiting was experimentally studied in C60 fullerene-based multicomponent solutions that are characterized by photoinduced electron-transfer processes with the formation of ion-radical pairs. The limitation efficiency in these solutions increased as a result of enhancement of absorption in the molecular system in an excited state. It was found that the spectral and time capabilities of limiters based on fullerene-containing media can be extended with the use of radical ions.Translated from Khimiya Vysokikh Energii, Vol. 39, No. 1, 2005, pp. 32–35.Original Russian Text Copyright © 2005 by Gryaznova, Danilov, Khrebtov, Shakhverdov.
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