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Total synthesis of (+)-tanikolide via oxidative lactonization |
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| Authors: | Schomaker Jennifer M Borhan Babak |
| Institution: | Department of Chemistry, Michigan State University, East Lansing, MI 48824, USA. borhan@cem.msu.edu |
| Abstract: | (+)-Tanikolide has been synthesized in eight linear steps with a 31% overall yield. The key step in the synthesis utilizes a recently developed tandem oxidative cleavage-lactonization of a precursor alkenol to deliver the lactone moiety. |
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