| 聚苯乙烯负载硒醚铂配位硅氢化催化剂 |
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| 引用本文： | 孟令芝,柯爱青.聚苯乙烯负载硒醚铂配位硅氢化催化剂[J].应用化学,1997,14(1):107-109. |
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| 作者姓名： | 孟令芝 柯爱青 |
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| 作者单位： | 武汉大学化学系 |
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| 摘 要： | 聚苯乙烯负载硒醚铂配位硅氢化催化剂孟令芝柯爱青陈远荫＊（武汉大学化学系武汉４３００７２）关键词聚苯乙烯，负载硒醚，铂配位，硅氢加成催化剂，铂配合物１９９６－０４－１８收稿，１９９６－１０－１８修回硒醚铂配合物早有报道［１］．刘秀芳等发现和研究了１０－...
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| 关 键 词： | 聚苯乙烯，负载硒醚，铂配位，硅氢加成催化剂，铂配合物 |
| 收稿时间： | 1996-04-18 |
Polystyrene Supported Selenoether Platinum Complex as Hydrosilylation Catalyst |
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| Meng Lingzhi,Ke Aiqing,Chen Yuanyin.Polystyrene Supported Selenoether Platinum Complex as Hydrosilylation Catalyst[J].Chinese Journal of Applied Chemistry,1997,14(1):107-109. |
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| Authors: | Meng Lingzhi Ke Aiqing Chen Yuanyin |
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| Institution: | Meng Lingzhi,Ke Aiqing,Chen Yuanyin * |
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| Abstract: | Polystyrene supported selenoethers were synthesized from chloromethylated crosslinked polystyrene and (HOCH 2CH 2) 2Se or EtOCH 2CH 2SeCH 2CH 2OH via Williamson reaction. They were reacted with potassium chloroplatinite in acetone under nitrogen atmosphere to give title complexes. It was found that the platinum complexes exhibited high catalytic activity in the hydrosilylation of olefins with triethoxysilane. |
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| Keywords: | polystyrene supported selenoether platinum coodination hydrosilylation catalyst platinum complex |
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