Self assembly of three new copper coordination polymers based on N-[(3-pyridine)-sulfonyl]aspartate: Synthesis and structure |
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| Authors: | B L Liao S X Li J J Guo J J Jia Y M Jiang |
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| Institution: | 1.College of Chemistry and Biological Engineering,Hechi University,Yizhou,P.R. China;2.College of Chemistry and Pharmacy,Guangxi Normal University,Guilin,P.R. China |
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| Abstract: | Three new copper coordination polymers Cu(L) · 6H2O] n (I), Cu2(L)2] n (II), and Cu(HL)2] n (III), where H2L is N-(3-pyridine)-sulfonyl]aspartate, have been synthesized and characterized by singlecrystal X-ray diffraction (CIF files CCDC nos. 1435871 (I), 1435872 (II), 1435873 III), elemental analysis and IR spectra. Moreover, the variable-temperature magnetic susceptibility had been studied for complex I. A structural comparison of these polymers suggests that different reaction temperatures play important role in the construction of resulting architectures for I–III. |
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