| The effect of polymerization conditions on crystalline of polybutene-1 catalyzed by metallocene catalyst |
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| 作者姓名： | Qi Gu Huang Ya Ping Sheng Kun Xue Deng Li Fu Ma Yi Xian Wu Wan Tai Yang State Key Laboratory of Chemical Resource Engineering College of Material Science and Technology Beijing University of Chemical Technology Beijing China |
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| 作者单位： | Qi Gu Huang，Ya Ping Sheng，Kun Xue Deng，Li Fu Ma，Yi Xian Wu，Wan Tai Yang State Key Laboratory of Chemical Resource Engineering，College of Material Science and Technology，Beijing University of Chemical Technology，Beijing 100029，China |
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| 摘 要： | Polybutene-1 was synthesized stereoselectively with the precursorη5-(pentamethyl-cyclopentadienyl) tribenzyloxide titanium (Cp*Ti(OBz)3) and methylaluminoxane (MAO). The effects of polymerization conditions, trimethyl alumina (TMA) content in MAO and temperature on the crystalline and molecular weight of the products, and catalytic activity were investigated. The structural properties of the polybutene-1 were characterized with 13C NMR and WAXD.
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| 收稿时间： | 31 August 2006 |
The effect of polymerization conditions on crystalline of polybutene-1 catalyzed by metallocene catalyst |
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| Qi Gu Huang,Ya Ping Sheng,Kun Xue Deng,Li Fu Ma,Yi Xian Wu,Wan Tai Yang State Key Laboratory of Chemical Resource Engineering,College of Material Science and Technology,Beijing University of Chemical Technology,Beijing ,China.The effect of polymerization conditions on crystalline of polybutene-1 catalyzed by metallocene catalyst[J].Chinese Chemical Letters,2007,18(2):217-220. |
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| Authors: | Qi Gu Huang Ya Ping Sheng Kun Xue Deng Li Fu Ma Yi Xian Wu Wan Tai Yang |
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| Institution: | State Key Laboratory of Chemical Resource Engineering, College of Material Science and Technology, Beijing University of Chemical Technology, Beijing 100029, China |
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| Abstract: | Polybutene-1 was synthesized stereoselectively with the precursor η5-(pentamethyl-cyclopentadienyl) tribenzyloxide titanium (Cp*Ti(OBz)3) and methylaluminoxane (MAO). The effects of polymerization conditions, trimethyl alumina (TMA) content in MAO and temperature on the crystalline and molecular weight of the products, and catalytic activity were investigated. The structural properties of the polybutene-1 were characterized with 13C NMR and WAXD. |
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| Keywords: | Metallocene catalyst Methylaluminoxane Polybutene-1 Structure |
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