Borohydrides of the alkali and alkaline-earth metals |
| |
| Authors: | L. V. Titov L. A. Gavrilova |
| |
| Affiliation: | 1. Institute of New Chemical Problems, Academy of Sciences of the USSR, Chernogolovka
|
| |
| Abstract: | | 1. | The interaction of borohydrides of the alkali and alkaline-earth metals (Li, Na, K, Mg, Ca, and Sr) with dihorane in diglyme medium at 0° and an initial pressure of B2H6 no higher than 600 mm was studied. | | 2. | It was established according to the data of the IR spectrum that all the investigated borohydrides, with the exception of calcium borohydride, react with diborane in diglyme with the formation of diborohydrides. | | 3. | In the interaction of calcium borohydride with B2H6, the addition of borane (BH3) occurs at one of the two BH4 groups, with the formation of the compound CaBH4B2H7 ·2DG. | | 4. | LiB2H7 · 2DG, NaB2H7 · 2DG, and CaBH4B2H7 · 2DG were isolated in the individual state. |
|
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
