Efficient water-soluble catalytic system RhI-CAP for biphasic hydroformylation of olefins |
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| Authors: | Oleg L. Eliseev Tatyana N. Bondarenko Sergey N. Britvin Polina P. Khodorchenko Albert L. Lapidus |
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| Affiliation: | 1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation;2. Department of Crystallography, St. Petersburg State University, 199034 St. Petersburg, Russian Federation;3. I. M. Gubkin Russian State University of Oil and Gas, 119991 Moscow, Russian Federation |
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| Abstract: | Rhodium-catalysed hydroformylation of styrene and aliphatic olefins under biphasic conditions in the presence of watersoluble 1,4,7-triaza-9-phosphatricyclo[5.3.2.14,9]tridecane (CAP) chemoselectively affords aldehydes. Multiple catalyst reuse without loss in performance is demonstrated. |
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| Keywords: | Corresponding author. |
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