| Formation and Photoelectrochemical Properties of Charge Transfer Complexes between Fullerene and Metallophthalocyanine |
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| 引用本文： | Zai Hong CHEN, Jun LIN, Juan LI, Hui ZHANG(Department of Chemistry,Xiamen University,Xiamen 361005). Formation and Photoelectrochemical Properties of Charge Transfer Complexes between Fullerene and Metallophthalocyanine[J]. 中国化学快报, 1999, 0(9) |
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| 作者姓名： | Zai Hong CHEN Jun LIN Juan LI Hui ZHANG(Department of Chemistry Xiamen University Xiamen 361005) |
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| 作者单位： | Department of Chemistry，Xiamen University，Xiamen 361005 |
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| 摘 要： | Fullerelleshavegeneratedarapidlygrowingandactiveresearchareabecauseoftheirunusualstructureandphysico-chemicalproperties.Fullerenes(C,.,.C,,)havehigherelectrollaffinity(2.75ev),soitiswellkllownthattheyareexcellentelectronacceptorsandhavealargenumberofcolljugatedrsbondswhichmayleadtolargenon-linearpolarizabilities'.C,,.,isreportedtoformchargetranstbrcomplexes(CTC)withappropriateelectrondonors,forexample,polymolecularPVK,y-cyclodextrin,aromaticandaliphaticammes'-3.Thecharge-transferinteraction…
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Formation and Photoelectrochemical Properties of Charge Transfer Complexes between Fullerene and Metallophthalocyanine |
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| Zai Hong CHEN, Jun LIN, Juan LI, Hui ZHANG. Formation and Photoelectrochemical Properties of Charge Transfer Complexes between Fullerene and Metallophthalocyanine[J]. Chinese Chemical Letters, 1999, 0(9) |
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| Authors: | Zai Hong CHEN Jun LIN Juan LI Hui ZHANG |
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| Abstract: | The formation of charge transfer complexes (CTC) between C60, with metallophtha- locyanine (MPc. M=Zn. Co) has been investigated in three mixed organic solvents,The MPc-C60CTC were characterized by using UV-Vis and fluorescence spectra. The formation equilibrium constants (K) of CTC and their stoichiometry were determined.The foundation of CTC leads to a remarkable cnhancement of the photoelectrochemical property,The CTC will provide a potentialopportunity to develop a new applicable photoelectric material. |
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| Keywords: | C60 metalllophthalocyaninc. photoclcctrochemical property. |
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