Synthesis and molecular structure of the first rhodium(I) complex containing a tetra-tert-butylcyclopentaphosphanide ligand |
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| Authors: | Schisler Andrea Lönnecke Peter Hey-Hawkins Evamarie |
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| Institution: | Institut für Anorganische Chemie der Universit?t Leipzig, Johannisallee 29, D-04103 Leipzig, Germany. |
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| Abstract: | Nacyclo-(P(5)(t)Bu(4))] (1) reacts with RhCl(PPh(3))(3)] (1:1) to give the first rhodium(I) complex with a tetra-tert-butylcyclopentaphosphanide ligand, Rh{cyclo-(P(5)(t)Bu(4))}(PPh(3))(2)] (2). 2 was characterized by NMR ((1)H, (13)C, (31)P), MS, IR, and X-ray structure determination. |
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