|
|||||
|
|
| Synthesis, characterization, photoluminescence and electroluminescence properties of new 1,3,4-oxadiazole-containing rhenium（I） complex Re（CO）3（Bphen）（PTOP） | |
| 作者姓名： | Yan Ping Wang Wen Fa Xie Bin Li Wen Lian Li |
| 作者单位： | Yan Ping Wang Wen Fa Xie Bin Li Wen Lian Li ~aPolyoxometalate Science Key Laboratory of Ministry of Education，Faculty of Chemistry，Northeast Normal University，Changchun 130024，China ~bKey Laboratory of Excited State Processes，Changchun Institute of Optics Fine Mechanics and Physics，Chinese Academy of Sciences，Changchun 130033，China ~cState Key Laboratory of Integrated Optoelectronics，Jilin University，Changchun 130012，China |
| 基金项目： | The authors gratefully thank the financial supports of the National Natural Science Foundations of China (No.20571071) and One Hundred Talents Project from Chinese Academy of Sciences. |
| 摘 要： | A new 1,3,4-oxadiazole-contanining rhenium(I) complex,with the formula Re(CO)_3(Bphen)(PTOP)],(Bphen=bathophe- nardine,PTOP=4-(5-p-tolyl-1,3,4-oxadiazd-2-yl)pyridine),is synthesized and characterized by elemental analysis,IR,~1H NMR, UV-vis and luminescence spectroscopy.The double-layer electroluminescence devices based on the Re(I) complex have been fabricated by spin-coating technique.The turn-on voltage,maximum efficiency,and brightness for green emission obtained from the devices are 9V,2.1cd/A and 165cd/m~2,respectively. |
| 关 键 词： | 铼（l） 络合物 丁酮二酸盐 电致发光 |
| 收稿时间： | 18 June 2007. |
Synthesis, characterization, photoluminescence and electroluminescence properties of new 1,3,4-oxadiazole-containing rhenium(I) complex Re(CO)3(Bphen)(PTOP) |
|
| Yan Ping Wang Wen Fa Xie Bin Li Wen Lian Li.Synthesis, characterization, photoluminescence and electroluminescence properties of new 1,3,4-oxadiazole-containing rhenium(I) complex Re(CO)3(Bphen)(PTOP)[J].Chinese Chemical Letters,2007,18(12):1501-1504. | |
| Authors: | Yan Ping Wang Wen Fa Xie Bin Li Wen Lian Li |
| Institution: | aPolyoxometalate Science Key Laboratory of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun 130024, China bKey Laboratory of Excited State Processes, Changchun Institute of Optics Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130033, China cState Key Laboratory of Integrated Optoelectronics, Jilin University, Changchun 130012, China |
| Abstract: | A new 1,3,4-oxadiazole-contanining rhenium(I) complex,with the formula Re(CO)_3(Bphen)(PTOP)],(Bphen=bathophe- nardine,PTOP=4-(5-p-tolyl-1,3,4-oxadiazd-2-yl)pyridine),is synthesized and characterized by elemental analysis,IR,~1H NMR, UV-vis and luminescence spectroscopy.The double-layer electroluminescence devices based on the Re(I) complex have been fabricated by spin-coating technique.The turn-on voltage,maximum efficiency,and brightness for green emission obtained from the devices are 9V,2.1cd/A and 165cd/m~2,respectively. |
| Keywords: | Rhenium(I) complex Oxadizole-founctionalized Electroluminescence |
| 本文献已被 CNKI 维普 ScienceDirect 等数据库收录！ | |