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Synthesis of methyl 3-deoxy-3-methylaminoarabinopyranoside,a component of some aminoglycoside antibiotics
Authors:Stacy W Remiszewski  Terry R Stouch  Steven M Weinreb
Institution:Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802 USA
Abstract:Amino sugar 1 has been synthesized in racemic form as a mixture of anomers from sorbic aldehyde. An intramolecular N-sulfinyl dienophile Diels-Alder strategy was used to stereospecifically generate the chiral centers of pentose 1.
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