Synthesis of methyl 3-deoxy-3-methylaminoarabinopyranoside,a component of some aminoglycoside antibiotics |
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Authors: | Stacy W Remiszewski Terry R Stouch Steven M Weinreb |
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Institution: | Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802 USA |
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Abstract: | Amino sugar has been synthesized in racemic form as a mixture of anomers from sorbic aldehyde. An intramolecular N-sulfinyl dienophile Diels-Alder strategy was used to stereospecifically generate the chiral centers of pentose . |
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