The fluoride ion effect in the reactions of singlet oxygen with enols |
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| Authors: | Harry H. Wasserman James E. Pickett |
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| Affiliation: | Department of Chemistry, Yale University, New Haven CT 06511, U.S.A. |
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| Abstract: | The fluoride ion effect in the reactions of enolic systems with singlet oxygen has been investigated. β-Dicarbonyl compounds yielded 1,2,3-tricarbonyl derivatives, some of which underwent further hydration, whereas α-diketones suffered oxidative decarboxylation to give open-chain aldehydo-acids or keto-acids. |
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