Computational analysis of the nucleophilic eliminative ring fission of bridgehead substituted 1,3-bishomocubyl acetates |
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| Authors: | P.M Ivanov E Ōsawa A.J.H Klunder B Zwanenburg |
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| Affiliation: | 1. Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060, Japan;2. Department of Organic Chemistry, University of Nijmegen, Toernooiveld, 6525 ED NijmegenThe Netherlands |
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| Abstract: | Molecular mechanics (MM2) calculations on the conceivable seco-cage structures by homoketonization of two types of bridgehead substituted 1,3-bishomocubyl acetates, viz. type A : 4-acetoxy-pentacyclo[5.3.0.02,5.03,9.04,8] decan-6-one and its ethylene ketal, and type B: 8-acetoxypentacyclo [5.3.0.02,5.03,9.04,8]decan-6-one, its ethylene ketal and 8-acetoxypentacyclo[5.3.0.02,5.03,9.04,8]decane were performed. |
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