Reduction electrochimique des derives carbonyles insatures : IX. Indanones et tetralones : electrolyses mixtes en presence d'electrophiles |
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| Authors: | Armelle Orliac-Le Moing Jacques Delaunay Alain Lebouc Jacques Simonet |
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| Affiliation: | 1. Laboratoire d''Electrochimie organique, U.A. CNRS n° 439 U.C.O., B.P. 808, 49005 Angers CédexFrance;2. Laboratoire d''Electrochimie organique, U.A. CNRS n° 439 Université de Rennes 1, B.P. 25 A, 35042 Rennes CédexFrance |
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| Abstract: | It is shown that activated cyclic carbonyl compounds, such as tetralones and indanones, can behave in a particular manner when they are reduced in presence of electrophiles. Two classes of electrophiles were chosen : alkyl halides and carbon dioxide. The reactivity (alkylation and carboxylation) often depends on the nature of the activated ketone used as a substrate. |
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