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Palladium-catalyzed addition reaction of polyhaloalkanes to olefins |
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| Authors: | Jiro Tsuji Koji Sato Hideo Nagashima |
| Institution: | Department of Chemical Engineering, Tokyo Institute of Technology, Meguro, Tokyo 152, Japan |
| Abstract: | Pd(OAc)2 combined with phosphines catalyzes homolytic cleavage of the C—Cl bond of CCl4 and CCl3CO2CH3 leading to facile addition to olefins under mild conditions. BrCCl3 also reacts with olefins to give 1,1,1-trichloro-3-bromoalkanes. The reaction is accelerated under CO atmosphere, and the presence of bases such as NaOAc or K2CO3 is essential to attain high yields of the adducts. |
| Keywords: | Present address:School of Materials Science Toyohashi University of Technology Tempaku-cho Toyohashi Aichi 440 Japan |
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