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Particle Size Limit for Concomitant Tuning of Size and Shape of Platinum Nanoparticles
Authors:Ceren Susut  Thuy Dang Nguyen  George B Chapman  YuYe Tong
Institution:(1) Department of Chemistry, Georgetown University, 37th & O Streets, NW, Washington, DC 20057, USA;(2) Department of Biology, Georgetown University, 37th & O Streets, NW, Washington, DC 20057, USA
Abstract:Based on a polyol process, one-step synthetic procedures were investigated for concomitant control of the shape and size of platinum nanoparticles (Pt NPs). Cubic and octahedral/tetrahedral particles of different sizes (5–10 nm) were synthesized using these procedures. Further attempts to control the shape of the NPs below 3–4 nm failed. It was found that 3–4 nm is the particle size limit for Pt NPs above which the particle size and shape can be concomitantly controlled.
Keywords:Pt nanoparticles  Shape and size control
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